Open Access

Nanostructured Bismuth Telluride Thermoelectric Generators for Sustainable Energy Harvesting in Solar Thermal Systems: Green Technology for Waste Heat Recovery

Priya jose, yesupriyarose@gmail.com
Center for Energy and Nano Research, Department of Physics, Karpagam Academy of Higher Education, Coimbatore, TN, India
Nagamani Prabu A, prabhu.spectra@gmail.com
Center for Energy and Nano Research, Department of Physics, Karpagam Academy of Higher Education, Coimbatore, TN, India
Debabrata Barik debabrata93@gmail.com
Department of Mechanical Engineering, Karpagam Academy of Higher Education, Coimbatore, TN, India,



J. Environ. Nanotechnol., Volume 15, No 1 (March 2026) pp. 616-624

https://doi.org/10.13074/jent.2026.03.2612092

PDF


Abstract

This study investigates nanostructured bismuth telluride (Bi₂Te₃) thermoelectric generators (TEGs) for sustainable waste heat recovery in solar thermal applications. Nanostructured Bi₂Te₃ materials were synthesized via hydrothermal methods and characterized using XRD, SEM, and TEM, demonstrating an improved figure of merit (ZT = 1.28 at 180℃) compared to conventional bulk materials (ZT = 0.95). The TEG modules incorporating these nanomaterials were deployed in a 200 m² pilot evacuated tube solar thermal system to exploit temperature gradients for electricity generation from waste heat. The hybrid system achieved a 4.9 percentage-point absolute improvement in overall system efficiency (67.9% to 72.8%), with the TEG modules contributing additional electrical output. Module-level thermoelectric conversion efficiency reached 5–8% at temperature differentials of 50–100℃. Environmental lifecycle assessment revealed significant carbon footprint reduction, with greenhouse gas payback achieved within the first year of operation and an energy payback period of 2.8 years. The nanostructured thermoelectric materials exhibited superior thermal stability over extended thermal cycling, validating long-term durability under realistic solar operating conditions. This work establishes nanomaterial-based TEG technology as a viable green solution for industrial waste heat recovery, contributing to sustainable energy systems.

Full Text

Reference


Aranguren, P., Astrain, D., Rodríguez, A. and Martínez, A., Experimental investigation of the applicability of a thermoelectric generator to recover waste heat from a combustion chamber, Appl. Energy, 152, 121–130(2015).

https://doi.org/10.1016/j.apenergy.2015.04.077

Bell, L. E., Cooling, heating, generating power, and recovering waste heat with thermoelectric systems, Sci., 321(5895), 1457–1461(2008).

https://doi.org/10.1126/science.1158899

Biswas, K., He, J., Blum, I. D., Wu, C. I., Hogan, T. P., Seidman, D. N., Dravid, V. P. and Kanatzidis, M. G., High-performance bulk thermoelectrics with all-scale hierarchical architectures, Nat., 489(7416), 414–418(2012).

https://doi.org/10.1038/nature11439

Champier, D., Thermoelectric generators: A review of applications, Energy Convers. Manage., 140, 167–181(2017).

https://doi.org/10.1016/j.enconman.2017.02.070

Dong, H., Popescu, R., Gerthsen, D. and Feldmann, C., Shape-stabilized Bi₂Te₃-capped tellurium nanorods, Zeitschrift für anorganische und allgemeine Chemie, 639, 2406-2410(2013).

https://doi.org/10.1002/zaac.201300536

Dresselhaus, M. S., Chen, G., Tang, M. Y., Yang, R. G., Lee, H., Wang, D. Z., Ren, Z. F., Fleurial, J. P. and Gogna, P., New directions for low-dimensional thermoelectric materials, Adv. Mater., 19(8), 1043–1053(2007).

https://doi.org/10.1002/adma.200600527

Gupta, S., Neeleshwar, S., Kumar, V. and Chen, Y., Synthesis of bismuth telluride nanostructures by refluxing method, Adv. Mater. Lett., 3(1), 50-54(2012).

https://doi.org/10.5185/amlett.2011.7285

He, W., Zhang, G., Zhang, X., Ji, J., Li, G. and Zhao, X., Recent development and application of thermoelectric generator and cooler, Appl. Energy, 143, 1–25(2015).

https://doi.org/10.1016/j.apenergy.2014.12.075

International Energy Agency, Solar Heat Worldwide 2025: Global Market Development. IEA Solar Heating and Cooling Programme. IEA report (2025).

https://www.iea-shc.org/solar-heat-worldwide

Kalogirou, S. A., Solar thermal collectors and applications, Prog. Energy Combus. Sci., 30(3), 231–295(2004).

https://doi.org/10.1016/j.pecs.2004.02.001

Kanta, S. K., Paul, S., Chatterjee, T., Dutta, H. and Pradhan, S. K., Microstructure and electrical characterization of thermoelectric nanocrystalline Bi₂Te₃ synthesized by mechanical alloying, Mater. Res., 22(4), 759-764(2019).

https://doi.org/10.1590/1980-5373-mr-2019-0328

Kraemer, D., Poudel, B., Feng, H. P., Caylor, J. C., Yu, B., Yan, X., Ma, Y., Wang, X., Wang, D., Muto, A., McEnaney, K., Chiesa, M., Ren, Z. and Chen, G., High-performance flat-panel solar thermoelectric generators with high thermal concentration, Nat. Mater., 10(7), 532–538(2011).

https://doi.org/10.1038/nmat3013

Mamur, H., Dilmac, O. F., Korucu, H. and Bhuiyan, M. Cost-effective chemical solution synthesis of bismuth telluride nanostructure for thermoelectric applications, Micro Nano Lett., 9(11), 1064-1074(2018).

https://doi.org/10.1049/mnl.2018.0116

Poudel, B., Hao, Q., Ma, Y., Lan, Y., Minnich, A., Yu, B., Yan, X., Wang, D., Muto, A., Vashaee, D., Chen, X., Liu, J., Dresselhaus, M. S., Chen, G. and Ren, Z., High-thermoelectric performance of nanostructured bismuth antimony telluride bulk alloys, Sci., 320(5876), 634–638(2008).

https://doi.org/10.1126/science.1156446

Rowe, D. M., Thermoelectrics and its Energy Harvesting, Boca Raton., 1120(2012).

https://doi.org/10.1201/b11869

Sarwar, S., Ali, S., Khan, S. R., Jamil, S., Farooq, S., Jafar, T., Latif, M. J. and Shehroz, H., Marriage of Green Technology and Chemistry – bismuth-based nanoparticles: a remarkable combination, Environ. Technol. Rev., 13(8), 544-571(2024).

https://doi.org/10.1080/21622515.2024.2380830

Shittu, S., Li, G., Yousef, G. A., Ayodele, E., Zhao, X. and Ma, X., Advancements in thermoelectric generators for enhanced performance, Renew. Sustain. Energy Rev., 109, 24-54(2020).

https://doi.org/10.1016/j.rser.2019.04.023

Snyder, G. J. and Toberer, E. S., Complex thermoelectric materials, Nat. Mater., 7(2), 105–114(2008).

https://doi.org/10.1038/nmat2090

Zhang, C., Mata, M., Li, Z., Belarre, F., Arbiol, J., Khor, K. A., Poletti, D., Zhu, B., Yan, Q. and Xiong, Q., Enhanced thermoelectric performance of solution-derived bismuth telluride-based nanocomposites via liquid-phase sintering, Nano Energy, 30, 630-638(2016).

https://doi.org/10.1016/j.nanoen.2016.10.056

Zhang, X. and Zhao, L. D., Thermoelectric materials: Energy conversion between heat and electricity, J. Materiomics, 1(2), 92–105(2015).

https://doi.org/10.1016/j.jmat.2015.01.001

Zhu, J., Wang, G., Zhu, W., Ou, L., Zheng, L., Zhang, J., Chen, J., Pan, J. and Wang, R., Efficient separation and purification method for recovering valuable elements from bismuth telluride refrigeration chip waste, ACS Omega, 8, 39222-39232(2023).

https://doi.org/10.1021/acsomega.3c04611

Powered by

Powered by OJS