Open Access

Optimization of Mechanical Properties of Cordia dichotoma/Alumina Nanoparticle Reinforced Epoxy Nanocomposites Under Alkali Treatment Using ANN Techniques

Ajinkya Prakash Edlabadkar, ajinkyae@gmail.com
Department of Mechanical Engineering, Yeshwantrao Chavan College of Engineering, Nagpur, MH, India
M. C. Madhu, madhumc@bmsit.in
Department of Mechanical Engineering, BMS Institute of Technology and Management, Avalahalli, Bangalore, KA, India
R. Arunbharathi, arunpsg09@gmail.com
Department of Mechanical Engineering, Sri Krishna College of Engineering and Technology, Kuniamuthur, Coimbatore, TN, India
Deepak Sharma, murughanandgoki@gmail.com
Department of Electronics and Communication Engineering, Jaypee university of Engineering and Technology, Raghogarh, Guna, MP, India
Narendra Singh, sriharinib7066@gmail.com
Department of Electronics and Communication Engineering, Koneru Lakshmaiah Education foundation, Guntur, AP, India
R. Revathi, rrevathi@kluniversity.in
Department of Electronics and Communication Engineering, Koneru Lakshmaiah Education foundation, Guntur, AP, India
S. Mayakannan kannanarchieves@gmail.com
Department of Mechanical Engineering, Rathinam Technical Campus, Coimbatore, TN, India
ORCID



J. Environ. Nanotechnol., Volume 14, No 2 (June 2025) pp. 525-540

https://doi.org/10.13074/jent.2025.06.2521549

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Abstract

The growing interest in natural fiber- and nano-filler-reinforced composites is driven by their excellent strength-to-weight ratio, recyclability, and environmental sustainability. This study aims to optimize key parameters influencing the mechanical performance of hybrid nanocomposites reinforced with Cordia dichotoma (CD) fibers and nano alumina (nAl₂O₃). The composites were fabricated using the conventional hand lay-up technique by varying the content of CD fiber (wt%), fiber length (mm), nAl₂O₃ content (wt%), and CD fiber alkali treatment duration. ASTM standards assess mechanical properties. The Taguchi optimization method was employed to identify optimal process parameters. Maximum tensile strength was achieved with 10 wt% Cordia dichotoma fiber (10 mm), 4 wt% nAl₂O₃, and 12 hours of NaOH treatment. Optimal flexural strength was obtained under similar conditions, with an 8-hour treatment, while the best impact strength was observed with a 15 mm fiber length, 6 wt% nAl₂O₃, and 12-hour alkali treatment. Experimental results closely aligned with artificial neural network (ANN) predictions, with deviations within 3-4%, confirming the model's predictive accuracy. ANOVA analysis revealed that fiber content, filler content, and alkali treatment contributed 4%, 1%, and 0.1%, respectively, to the variation in properties, with fiber content yielding approximately 90% influence. The close agreement between experimental data and ANN forecasts highlights the potential of ANN-based models for predicting mechanical behavior and optimizing composite design. This approach provides valuable insights for enhancing reliability and predicting service life in various industrial applications.

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Reference


Amjad, A., Abidin, M. S. Z., Alshahrani, H. and Rahman, A. A. A., Effect of Fibre Surface Treatment and Nanofiller Addition on the Mechanical Properties of Flax/PLA Fibre Reinforced Epoxy Hybrid Nanocomposite, Polymers, 13(21), 3842 (2021).

https://doi.org/10.3390/polym13213842

Aruna, M., Rajan, V. V., Prabagaran, S., Karthikeyan, N., Anderson, A., Venkatesh, R., Mohanavel, V., Al-Obaid, S. and Salmen, S. H., Featuring of alumina nanoparticle and NaOH treated flax fiber on function properties of polypropylene composites, J. Polym. Res., 32(2), 35 (2025).

https://doi.org/10.1007/s10965-025-04262-x

Arunachalam, S. J., Saravanan, R., Sathish, T., Giri, J. and Barmavatu, P., Optimization of nano-filler and silane treatment on mechanical performance of nanographene hybrid composites using RSM and ANN technique, J. Adhes. Sci. Technol., 39(2), 257–280 (2025).

https://doi.org/10.1080/01694243.2024.2403680

Boumaaza, M., Belaadi, A. and Bourchak, M., The Effect of Alkaline Treatment on Mechanical Performance of Natural Fibers-reinforced Plaster: Optimization Using RSM, J. Nat. Fibers, 18(12), 2220–2240 (2021).

https://doi.org/10.1080/15440478.2020.1724236

Diharjo, K., Andoko, A., Soedarsono, J. W., Gapsari, F., Rangappa, S. M. and Siengchin, S., Enhanced composite performance: Evaluating silane treatment on Cordia dichotoma Fibers, Results Eng., 25, 104260 (2025).

https://doi.org/10.1016/j.rineng.2025.104260

Egala, R. and Gangi, S. S., Influence of surface modifications of Castor oil fibre on mechanical properties of fibre reinforced Epoxy composites, Adv. Mater. Process. Technol., 8(2), 724–762 (2022).

https://doi.org/10.1080/2374068X.2021.1959107

El-Oudiani, A., Glouia, Y., Ben, S. R., Tlija, M., Khalifa, A., Msahli, S. and Sakli, F., Effect of alkali treatment and fibre length on agave/mortar composite properties, Ind. Crops Prod., 222119530 (2024).

https://doi.org/10.1016/j.indcrop.2024.119530

Hassan, G., Bhatti, I. and Shaikh, M., Investigating the Influence of Alkali over Morphology Functional Groups and Physical and Mechanical Properties of Fiber obtained from Cordia dichotoma (Gum Berry), Phys. Chem. Res., 12(2), 349-359 (2024).

https://doi.org/10.22036/pcr.2023.408365.2381

Jayaraman, R., Girimurugan, R., Suresh, V., Shilaja, C. and Mayakannan, S., Improvement on Tensile Properties of Epoxy Resin Matrix Sugarcane Fiber and Tamarind Seed Powder Reinforced Hybrid Bio-Composites, ECS Trans., 107(1), 7265–7272 (2022).

https://doi.org/10.1149/10701.7265ecst

Justin, A. B. S., Arul, S. J., Thandavamoorthy, R. and Devarajan, Y., Elevating mechanical and thermal performance on alkali-treated pineapple/glass fibre sandwich composite, Polym. Int., 74(2), 170–177 (2025).

https://doi.org/10.1002/pi.6705

Kabir, M. F., Hossain, M. A., Tamanna, M. S., Kader, G. M. U. and Sakib, S. S., Investigation of the Impact of Epoxy-based Composites Reinforced with Betel Nut and Coir Fiber on Physio-Mechanical Properties,

https://doi.org/10.24423/ENGTRANS.3404.2024

Keerthiveettil, R. S., Vijayananth, K., Arivendan, A. and Ammarullah, M. I., Evaluating the effects of pineapple fiber, potato waste filler, surface treatment, and fiber length on the mechanical properties of polyethylene composites for biomedical applications, Results Eng., 24102974 (2024).

https://doi.org/10.1016/j.rineng.2024.102974

Khelifi, A., Boumaaza, M., Belaadi, A., Tarek, D., De Azevedo, A.R.G., Bourchak, M. and Jawaid, M., Effects of alkaline treatment of Washingtonia mesh waste on the mechanical and physical properties of bio-mortar: experimental and prediction models, Biomass Convers. Biorefinery, 14(9), 10621–10650 (2024).

https://doi.org/10.1007/s13399-023-04221-w

Madhusudhan, R. B., Harisankar, P., Suresh, K. G., Meenakshi, R. R., Ananthakrishna, N. and Mohan, R. Y. V., Enhancement of mechanical and structural characteristics through the hybridization of carbon fiber with Cordia‐dichotoma/polyester composite, Polym. Compos., 46(2), 1803–1814 (2025).

https://doi.org/10.1002/pc.29074

Mohit, H., Sanjay, M.R., Siengchin, S., Kanaan, B., Ali, V., Alarifi, I.M. and El-Bagory, T.M.A.A., Predicting physico-mechanical and thermal properties of loofa cylindrica fibers and Al2O3/Al-SiC reinforced polymer hybrid composites using artificial neural network techniques, Constr. Build. Mater., 409, 133901 (2023).

https://doi.org/10.1016/j.conbuildmat.2023.133901

Natrayan, L., Kaliappan, S., Sethupathy, B. S., Sekar, S., Patil, P. P., Velmurugan, G. and Tariku, O. T., Effect of Mechanical Properties on Fibre Addition of Flax and Graphene-Based Bionanocomposites, Int. J. Chem. Eng., 20, 221–8 (2022).

https://doi.org/10.1155/2022/5086365

Rajakumar, I. P. T., Raguraman, D., Isaac, J. S., Suthan, R., Bhattacharya, S., Seikh, A. H., Khan, S. M. A. and Raghavan, I. K., Mechanical Properties of Polymer Composites Reinforced with Alkaline-Treated Natural Fibre, Adv. Polym. Technol., 20, 221–7 (2022).

https://doi.org/10.1155/2022/1458547

Rajkumar, A., Selvan, M. T. G. A., Neto, V., Raja, R. S., Binoj, J. S. and Bright, B. M., Optimization and statistical analysis on mechanical, thermal, wear and water-absorption characteristics of fragrant screwpine fiber-reinforced polymer biocomposites, Iran. Polym. J., 34(3), 399–412 (2025).

https://doi.org/10.1007/s13726-024-01377-8

Rajeshkumar, G., Mechanical, free vibration, electrical and water absorption properties of vinyl ester composites reinforced with Phoenix sp. fibers: Influence of eco‐friendly sodium bicarbonate treatment, Polym. Compos., 46(3), 2781–2793 (2025).

https://doi.org/10.1002/pc.29139

Salih, W., Mechanical Properties of Chemical Treated Jute Fiber Reinforced Polymer Composites, Mater. Sci. Forum, 100, 275–83 (2020).

https://doi.org/10.4028/www.scientific.net/MSF.1002.75

Senthil, K. M. S., Sivakumar, M., Senthil, S. M. and Rajeshkumar, L., Effect of alumina fillers on physical and mechanical properties of luffa/groundnut shell natural fiber reinforced polymer composites, Polym. Compos., 45(11), 10457–10469 (2024).

https://doi.org/10.1002/pc.28487

Sumesh, K. R. and Kanthavel, K., The influence of reinforcement, alkali treatment, compression pressure and temperature in fabrication of sisal/coir/epoxy composites: GRA and ANN prediction, Polym. Bull., 77(9), 4609–4629 (2020).

https://doi.org/10.1007/s00289-019-02988-5

Thangaraj, S., Pradeep, Gm., Heaven, D., Mayakannan, S. and Benham, A., Experimental investigations on tensile and compressive properties of nano alumina and arecanut shell powder reinforced polypropylene hybrid composites, Mater. Today Proc., 68, 2243–2248 (2022).

https://doi.org/10.1016/j.matpr.2022.08.442

Zhao, H., Tang, J., Li, Z., Zhou, T. and Xiong, T., Experimental study on the static properties of bamboo fiber reinforced ultra-high performance concrete (UHPC), Constr. Build. Mater., 453138974 (2024).

https://doi.org/10.1016/j.conbuildmat.2024.138974

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