Improving Performance of Eco-friendly Perovskite Solar Cells with Fluorine Tin Oxide/Gold Nanolayers-doped Dual Optical Absorber
J. Environ. Nanotechnol., Volume 14, No 3 (September 2025) pp. 39-43
Abstract
Recently, perovskite solar cells are extensively studied in photovoltaics owing to their cost-effectiveness and high power conversion efficiencies. In this report, the performance of a lead-free perovskite solar cells with double optical absorbers of copper indium gallium selenide (CIGS) and methylammonium tin triiodide (MASnI3) is studied using SCAPS-1D simulation. The proposed device included Spiro-OmeTAD as the electron transport layer due to its high electron mobility and suitable energy level alignment and ZnO as the hole transport layer due to its good hole mobility and good chemical stability. Fluorine-doped tin oxide and gold were used as the front and back electrode, respectively, with cadmium sulfide being used as the buffer layer. The use of p-type CIGS and MASnI3 as dual absorbers enhanced light absorption and charge production, results in a power conversion efficiency of 36.4%, open circuit voltage (Voc) of 1.38 V at a fill factor of 54.2% and a short circuit current density (Jsc) of 48.3 mA/cm2. The findings demonstrate the potential of dual absorber layer engineering to enhance the efficiency of ecologically friendly perovskite solar technologies.
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Reference
Ahmad, O., Qasim, I., Hasnain, S. M., Abdin, Z. U., Nasir, M. F., Malik, M. I. and Rashid, A., Modelling and numerical simulations of eco-friendly double absorber solar cell Spiro-OmeTAD/CIGS/MASnI3/CdS/ZnO and its PV-module, Org Electron., 117, 106781 (2023).
https://doi.org/10.1016/j.orgel.2023.106781
Bailie, C. D. and McGehee, M. D., High-efficiency tandem perovskite solar cells, MRS Bull., 40, 681-685 (2015).
https://doi.org/10.1557/mrs.2015.167
Chen, Q., Wang, Y., Zheng, M., Fang, H. and Meng, X., Nanostructures confined self-assembled in biomimetic nanochannels for enhancing the sensitivity of biological molecules response, J. Mater. Sci. Mater. Electron., 29, 19757-19767 (2018).
https://doi.org/10.1007/s10854-018-0101-2
Han, Q., Hsieh, Y. T., Meng, L., Wu, J. L., Sun, P., Yao, E. P., Chang, S. Y., Bae, S. H., Kato, T., Bermudez, V. and Yang, A. Y., High-performance perovskite/Cu(In,Ga)Se2 monolithic tandem solar cells, Sci., 361(6405), 904-908 (2018).
https://doi.org/10.1126/science.aat5055
Hasnain, S. M., Examining the advances, obstacles, and achievements of tin-based perovskite solar cells: A review, Sol. Energy., 262, 111825 (2023).
https://doi.org/10.1016/j.solener.2023.111825
Hasnain, S. M., Iqbal, A., Qasim, I., Irshad, K., Mir, M. A., Malik, M. I. and Sundar, L. S., Performance evaluation of organometal halide MASnI3 and inorganic BaZrS3 hybrids in perovskites solar cells: Theoretical approach, Hybrid Adv., 9, 100408 (2025).
https://doi.org/10.1016/j.hybadv.2025.100408
Jiang, T., Wang, Y., Meng, D., Wu, X., Wang, J. and Chen, J., Controllable fabrication of CuO nanostructure by hydrothermal method and its properties, Appl. Surf. Sci., 311, 602-608 (2014).
https://doi.org/10.1016/j.apsusc.2014.05.116
Jošt, M., Betram, T., Koushik, D., Marquez, J. A., Verheijen, M. A., Heinemann, M. D., Kohnen, E., Ashouri, A. A., Braunger, S., Lang, F., Rech, B., Unold, T., Creatore, M., Lauermann, I., Kaufmann, C. A., Schlatmann, R. and Albrecht, S., 21.6%-efficient monolithic perovskite/Cu(In,Ga)Se2 tandem solar cells with thin conformal hole transport layers for integration on rough bottom cell surfaces, ACS Energy Lett., 4(2) 583-590 (2019).
https://doi.org/10.1021/acsenergylett.9b00135
Kojima, A., Teshima, K., Shirai, Y. and Miyasaka, T., Organometal halide perovskites as visible-light sensitizers for photovoltaic cells, J. Am. Chem. Soc., 131(17) 6050-6051 (2009).
https://doi.org/10.1021/ja809598r
Liu, J., Chen, K., Khan, S. A., Shabbir, B., Zhang, Y., Khan, Q. and Bao, Q., Synthesis and optical applications of low dimensional metal-halide perovskites, Nanotechnol., 31(15), 152002 (2020).
https://doi.org/10.1088/1361-6528/ab5a19
Qasim, I., Ahmad, O., Abdin, Z. U., Rashid, A., Nasir, M. F., Malik, M. I., Rashid, M. and Hasnain, S. M., Design and numerical investigations of eco-friendly, non-toxic (Au/CuSCN/CH3NH3SnI3/CdTe/ZnO/ITO) perovskite solar cell and module, Sol. Energy., 237, 52-61(2022).
https://doi.org/10.1016/j.solener.2022.02.056
Raj, A., Kumar, M., Bherwani, H., Gupta, A. and Anshul, A., Evidence of improved power conversion efficiency in lead-free CsGeI3 based perovskite solar cell heterostructure via scaps simulation, J. Vac. Sci. Technol. B., 39(1), 012401(2021).
https://doi.org/10.1116/6.0000718
Saikia, D., Bera, J., Betal, A. and Sahu, S., Performance evaluation of an all inorganic CsGeI3 based perovskite solar cell by numerical simulation, Opt. Mater., 123, 111839 (2022).
https://doi.org/10.1016/j.optmat.2021.111839
Shen, Y., Ran, C., Dong, X., Wu, Z. and Huang, W., Dimensionality engineering of organic–inorganic halide Perovskites for next‐generation X‐ray detector, Small., 20(16), 2308242 (2024).
https://doi.org/10.1002/smll.202308242
Singh, N., Chaudhary, A.K., Saxena, S.K., Saxena, M. and Rastogi, N., Electrical simulation of organic solar cell at different charge carrier mobility, IOSR J. Appl. Phys., 09(02), 01-04 (2017).
https://doi.org/10.9790/4861-0902020104
Yoshikawa, K., Kawasaki, H., Yoshida, W., Irie, T., Konishi, K., Nakano, K., Uto, T., Adachi, D., Kanematsu, M., Uzu, H. and Yamamoto, K., Silicon heterojunction solar cell with interdigitated back contacts for a photoconversion efficiency over 26%, Nat. Energy, 2, 17032(2017).
https://doi.org/10.1038/nenergy.2017.32
Wang, Y., Jiang, T., Meng, D., Yang, J., Li, Y., Ma, Q. and Han, J., Fabrication of nanostructured CuO films by electrodeposition and their photocatalytic properties, Appl. Surf. Sci., 317, 414-421 (2014).
https://doi.org/10.1016/j.apsusc.2014.08.144
Wu, J., Li, Y., Yiming, L., Xie, W., Shi, J., Li, D., Cheng, S. and Meng, O., Using hysteresis to predict the charge recombination properties of perovskite solar cells, J. Mater. Chem. A., 9(10), 6382-6392 (2021).
https://doi.org/10.1039/D0TA12046D
Zhou, Y. and Gray-Weale A., A numerical model for charge transport and energy conversion of perovskite solar cells, Phys. Chem. Chem. Phys., 18(6), 4476-4486 (2016).
