Welcome to JENT its Thursday 18th of January 2018

Journal of Environmental Nanotechnology

(A Quarterly Peer-reviewed and Refereed International Journal)
ISSN(Print):2279-07 48; ISSN(Online):2319-5541
CODEN:JENOE2

Structural, Morphological and Optical Properties: CeO2 Nanoparticles Prepared through the Azadirachta indica Leaf Extract by Green Method

Abstract

The CeO2 NPs were derived from Azadirachtaindica(A.indica) leaf extracts. The X-ray diffraction studies confirmed that synthesized CeO2 NPs were exhibited the cubic structure. In XPS spectra, the oxidation states of each element were identified for CeO2 NPs. The Raman active mode was observed at 461cm-1 and this was due to the symmetrical stretching mode of the Ce-8O for CeO2 NPs. From FESEM and TEM images, the CeO2 NPs were exhibited spherical structure. From the EDAX spectra, the elemental compositions were identified. The optical studies were carried out using UV-Vis and Photoluminescence spectra for CeO2 NPs respectively.

Article Type: Research Article

Corresponding Author: S. Parvathy 1  

Email:

This article has not yet been cited.

S. Parvathy 1*,  B. R. Venkatraman 2.  

1. *1Department of Chemistry, Government Arts College (Autonomous), Salem, TN, India.

2. 2Department of Chemistry, Periyar E.V.R.College (Autonomous), Tiruchirappalli, TN, India.

J. Environ. Nanotechnol., Volume 6, No. 4 pp. 47-51
ISSN: 2279-0748 ISSN eISSN: 2319-5541
ENT174286.pdf
Download Citation

Reference

Arumugam, A., Karthikeyan, C., Haja Hameed, A. S., Gopinath, K., Gowri, S. and Karthika V.,  Synthesis of cerium oxide nanoparticles using Gloriosasuperba L. leaf extract and their structural, optical and antibacterial properties, Mater. Sci. Eng. C.,  49(1), 408-415(2015).

doi:10.1016/j.msec.2015.01.042

Amorshed, A. H., Moussa, M. E., Bedair, S. M., Leonard, R., Liu, S.X. and El-Masry, N., Violet/blue emission from epitaxial cerium oxide films on silicon substrates, Appl. Phy. Lett.,70(13), 1647-1649(1997).

doi:10.1063/1.118658

Czerwinski, F. and Szpunar, J. A., The nanocrystalline ceria sol-gel coatings for high temperature applications, J. Sol-Gel Sci. Technol., 9(1),103-114(1997).

doi:10.1023/A:1026420609370

Hu, J. D., Li, Y. X., Zhou, X. Z. and Cai, M. X., Preparation and characterization of ceria nanoparticles using crystalline hydrate cerium propionate as precursor, Mater. Lett., 61(28), 4989-4992(2007).

doi:10.1016/j.matlet.2007.03.097

Huang, Y., Cai, Y., Qiao, D. and Liu, H., Morphology-controllable synthesis and characterization of CeO2 nanocrystals, Particuology, 9(2), 170-173(2011).

doi:10.1016/j.partic.2010.07.023

Kim, C. G., Green emission from cerium hydroxide layers formed in Si/In/CeO2/Si structures,Appl. Phy. Lett.,79(19), 3047-3049(2001).

doi: 10.1063/1.1416161

Liao, X. H., Zhu, J. M., Zhu, J. J. and Xu, J. Z., Chen, H.Y., Preparation of monodispersed nanocrystalline CeO2 powders by microwave irradiation. Chem.Commun.,10, 937-938 (2001).

doi: 10.1039/b101004m

Lu, X. H., Huang, X., Xie, S. L., Zheng, D. Z., Liu, Z.Q., Liang, C.L. and Tong, Y.X., Facile electrochemical synthesis of single crystalline CeO2 octahedrons and their optical properties. Langmuir, 26(10),7569-7573 (2010).

doi: 10.1021/la904882t

Miki, T., Ogawa, T., Haneda, M., Kakuta, N., Ueno, A., Tateishi, S., Matsuura, S. and Sato, M., Enhanced oxygen storage capacity of cerium oxides in cerium dioxide/lanthanum sesquioxide/aluminacontaining precious metals. J. Phys. Chem., 94(16):6464-6467 (1990).

doi: 10.1021/j100379a056

Si, R., Zhang, Y. W., You, L. P. and Yan, C. H., RareEarth Oxide Nanopolyhedra, Nanoplates, and Nanodisks. Angew. Chem. Int. Ed.,117(21):3320-4 (2005).

doi: 10.1002/anie.200462573

Tsunekawa, S., Fukuda, T. and Kasuya, A., Blueshift in ultraviolet absorption spectra of monodisperse CeO2−x nanoparticles. J. Appl. Phys., 87(3):1318-21 (2000).

doi:10.1063/1.372016

Wang, Z. L. and Feng, X., Polyhedral shapes of CeO2 nanoparticles, J. Phys. Chem. B., 107(49), 13563-13566 (2003).

doi: 10.1021/jp036815m

Wang, H., Zhu, J.J., Zhu, J.M., Liao, X.H., Xu, S., Ding, T. and Chen, H.Y., Preparation of nanocrystalline ceria particles by sonochemical and microwave assisted heating methods. Phys. Chem. Chem. Phys., 4(15), 3794-3799(2002).

doi: 10.1039/b201394k

Wang, L., Ren, J., Liu, X., Lu, G. and Wang, Y., Evolution of SnO2 nanoparticles into 3D nanoflowers through crystal growth in aqueous solution and its optical properties. Mater.Chem.Phys.,127(1),114-119 (2011).

doi:10.1016/j.matchemphys.2011.01.043

Yao, S. Y. and Xie, Z. H., Deagglomeration treatment in the synthesis of doped-ceria nanoparticles via coprecipitation route,J. Mater.Process. Tech.,186(1), 54-59 (2007).

doi:10.1016/j.jmatprotec.2006.12.006

Yu, T., Joo, J., Park, Y. I. and Hyeon, T., Large‐Scale Nonhydrolytic Sol–Gel Synthesis of Uniform‐Sized Ceria Nanocrystals with Spherical, Wire, and Tadpole Shapes. Angew. Chem., 117(45):7577-80 (2005).

doi: 10.1002/anie.200500992

Zhang, Y. W., Si, R., Liao, C. S., Yan, C. H., Xiao, C.X. and Kou, Y., Facile alcohothermal synthesis, size-dependent ultraviolet absorption, and enhanced CO conversion activity of ceria nanocrystals. J.Phys. Chem. B,107(37), 10159-67 (2003).

doi: 10.1021/jp034981o

Zhang, F., Chan, S. W., Spanier, J. E., Apak, E., Jin, Q., Robinson, R.D. and Herman, I.P., Cerium oxide nanoparticles: size-selective formation and structure analysis. Appl. Phy.Let.,80(1), 127-129 (2002).

doi:10.1063/1.1430502

>>