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Journal of Environmental Nanotechnology

(A Quarterly Peer-reviewed and Refereed International Journal)
ISSN(Print):2279-07 48; ISSN(Online):2319-5541
CODEN:JENOE2

Separation of Toxic Metal Ions Such as Pb(II), Cu(II) and Hg(II) from Industrial Waste Water Using Newly Synthesised in Zirconium molydophosphate Cation Exchange

Abstract

A novel four component inorganic cation exchange material tinzirconium molybdophosphate with two cations and two anions has been synthesized. Chemical composition of he compound was determined by ICP-AES method and structural studies were carried out using TGA, XRD, and FT-IR, SEM. Bifunctional behaviour of the material has been indicated by its pH titration curves. The material shows high ion exchange capacity of 1.96 meqg-1. The distribution coefficient studies of metal ions on the material were performed in different solvent systems and the material was found to be selective for Pb(II), Cu(II) and Hg(II) ions. On the basis of distribution coefficient value, some analytically important binary separations of metal ion like Pb(II)-Co(II), Pb(II)-Ni(II), Pb(II)-Mg(II), Pb(II)-Hg(II), Cu(II)- Bi(III), Cu(II)-Zn(II), Cu(II)-Mg(II), Hg(II)-Zn(II), Hg(II)-Bi(III), Hg(II)-Mg(II) were achieved on tinzirconium molybdophosphate column. In order to demonstrate the practical utility of the material, quantitative separation of Pb(II), Cu(II) and Hg(II) from textile effluent, paper industry and wood industry have been achieved.

Article Type: Orginal Research Article

Corresponding Author: P. Vinisha Valsaraj 1  

Email: vinipunep@gmail.com

P. Vinisha Valsaraj 1*,  C. Janardanan 2.  

1, 2. Department of Chemistry, Sree Narayana College, Kannur, Kerala, India.

J.Environ. Nanotechnol., Volume 2, (2013) pp. 06-14
ISSN: 2279-0748 eISSN: 2319-5541
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Reference

Rao, B.S., Madec, P.J., Marechal, E., Synthesis of Vinyl Ester Resins, Polymer Bulletin, 16,153- 157, (1986).http://dx.doi.org/10.1007/BF00955485

Cassidy, P.E., Thermally Stable Polymers, Synthesis and Properties, Marcel Dekker, New York , p.2, (1980).

Sonti, S.S. and Barbero, E.J., “Material Characterisation of Pultruded Laminates and
Shapes”, Journal of Reinforced Plastic and Composites, 15: 701-717 (1996).

Singh, B. P., Jain R. C., Bhardwaj, I. S., J. Poly. Sci., 2, 941,(1994).

Brown, J. R., Mathys, Z., Composites, Volume28(A), issue 7, 675, (1997).

Hag, N., Harrison, P., Corrosion Preventing & Control, 43, 162, (1996).

Sharmilla, R.J., Premkumar, S., Alagar, M., J. Appl. Poly. Sci., 103, 167-177, (2007).http://dx.doi.org/10.1002/app.25038

Manson, J., Wakeman, M., Bernet, N., Comprehensive Composite Material, Amsterdam 2, 577, (2000).http://dx.doi.org/10.1016/B0-08-042993-9/00167-4

Kelley ,D.H. and Percy J.F., Polymer Composites, 18, 34, (1997).