Open Access

Electrodeposition of Transition Metal-influenced Magnetic Alloys and its Microstructural Properties

K. Antonyraj, antonyrajphy@gmail.com
Department of Physics, Government Arts College, Coimbatore, TN, India.
M. Ezhil Inban, Department of Physics, Government Arts College, Coimbatore, TN, India. P. Rajesh Department of Physics, Chikkanna Government Arts College, Tiruppur, TN, India


J. Environ. Nanotechnol., Volume 9, No 2 (2020) pp. 20-23

https://doi.org/10.13074/jent.2020.06.202407

PDF


Abstract

Magnetic alloy coatings exhibit admirable magnetic properties and corrosion resistance; however, their applications are restricted due to complexities in the preparation process and high costs involved. In the present work, an attempt has been made to prepare cobalt alloys with other transition metals through a simple Electrodeposition method. In order to attain cobalt-rich alloys, appropriate chloride salts were chosen as precursors. After the deposition process, the deposited alloys were carried out for microstructural characterization. EDAX pattern of the prepared alloys confirmed the presence of relevant elements at a higher percentage; morphology properties of the films confirmed the even and crack-free coatings. The corrosion resistance of the prepared alloys was investigated in an acidic medium and it was found to be better when compared with the empty substrate. It was concluded that the Electrodeposition process has greater potential in producing alloys with better purity than other methods.

Full Text

Reference


Asutosh Kumar Pandey, Electrochemical deposition and characterization of Fe–Zn alloys, International Journal of Advances in Pharmacy, Biology and Chemistry, 2(1), 170-172 ( 2013).

Baldwin, K. R. and Smith, C. J. E., Advances in Replacen1ents for Cadmium Plating in Aerospace Applications, Trans. Inst. Met. Finish, 74, 202-208 (1996).

https://doi.org/10.1080/00202967.1996.11871127

Baskar, T., Rajni, K. S. and Kannan, R., Synthesis and structural characterization of electro deposited nickel cobalt tungsten alloy thin film at different temperature, Int. J. Adv. Sci. Eng., 3(11), 378–387 (2014).

Dimitra Vernardou, Emmanouil Spanakis, Nikolaos Katsarakis, Emmanouil Koudoumas, Electrodeposition of V2O5 using ammonium metavanadate at room room temperature, Adv. Mat. Lett. 5(10), 569-572(2014).

https://doi.org/10.5185/amlett.2014.5577

Ezhil Inban Manimaran, Antonyraj, K., Emerson Rajamony Navaneetha, Sathish kumar, V., Rajesh, P., Influence of different conducting substrates on magnetic properties of electrodeposited Ni–Fe thin films, J. Mater. Sci. Mater Electron., 29, 3715- 3721(2018).

https://doi.org/10.1007/s10854-017-8304-5

Kannan, R. and Kokila, S., Synthesis and Structural Characterization of CoNiW alloy Thin Films by Electrodeposition, Int. J. Thin Fil. Sci. Tec., 4(1), 59-62 (2015).

https://doi.org/10.12785/ijtfst/040111

Kwang Pyo Chae, Synthesis and Magnetic Properties of Electrodeposited Cobalt-Iron-Vanadium Thin Films, Journal of Magnetics, 11(2), 87-89 (2006).

https://doi.org/10.4283/JMAG.2006.11.2.087

Landolt, D. J., Electrodeposition science and technology in the last quarter of the twentieth century, J. Electrochem. Soc., 149(3), S9-S20 (2002).

https://doi.org/10.1149/1.1469028

Manimaran, E. I. and Navaneetha, E. R., Structural influence of copper substrate on magnetic properties of electrodeposited CoPtP films for MEMS applications, J. Mater. Sci., 26(12), 9821–9826, (2015).

https://doi.org/10.1007/s10854-015-3655-2

Mohan, K., Kadiresan, R. and Senthilkumar, V., Synthesis and Characterization of Fe-Ni-Co magnetic thin films at different bath temperature, Int. J. Adv. Res. Sci., Eng., 5(7), 285–292 (2016).

Prabhu Ganesan, Swaminatha P. Kumaraguru, Branko N. Popov, Development of Zn–Ni–Cd coatings by pulse electrodeposition process, Surface & Coatings Technology, 201 3658–3669(2006).

https://doi.org/10.1016/j.surfcoat.2006.08.143

Raj Kumar, R., Gowrisankar, P., Ezhil Inban Manimaran, Rajesh, P., Antonyraj, K., Influence of Phosphorous in Magnetic and Corrosion Properties of Electrodeposited Cobalt based Multinary Alloys, International Journal for Research in Applied Science & Engineering Technology, 7(9), 224-233, (2019).

https://doi.org/10.22214/ijraset.2019.9033

Sundaram, K., Raja, M., Thanikaikarasan, S., Chu, J. P. and Mahalingam, T., Role of pH and current density in electrodeposited soft magnetic Co-Ni-Fe alloy thin films, Materials Science-Poland, (29), 165-170 (2011).

https://doi.org/10.2478/s13536-011-0037-1

Xu-Ming Sun, Quan Yuan Dong-Ming Fang, Hai-Xia Zhang, Electrodeposition and Characterization of CoNiMnP-based Permanent Magnetic Film for MEMS Applications, Proceedings of the 2011 6th IEEE International Conference on Nano/Micro Engineered and Molecular Systems, 367-371, (2011).

https://doi.org/10.1109/NEMS.2011.6017369

Contact Us

  • No. 53, II Street,
    Rock Mount City, Erode,
    TN, India - 638112
  • editorjent@gmail.com
  • +91 94422 64501

Powered by

Powered by OJS