Open Access

Growth, Structure, Spectral Characterization, Fluorescence and Thermal Studies on Phenyltrimethylammonium Trichloro Cadmiate (II) Crystals

V. Mohanraj, chemistrymohan@gmail.com
Department of Chemistry, Manonmaniam Sundaranar University Constituents College, Kanniyakumari, TN, India.
M.Thenmozhi, Department of Physics, Bangalore City College, Bangalore, Karnataka, India. R. Pavithra, Department of Chemistry, Government Arts College (Autonomous), Coimbatore, TN, India. Jaslin J. Christopher, Department of Chemistry, Manonmaniam Sundaranar University Constituents College, Kanniyakumari, TN, India. A. S. Jebamalar, Department of Physics, Nesamony Memorial Christian College, Marthandam, TN, India. R. Umarani Department of Chemistry, Government Arts College (Autonomous), Coimbatore, TN, India.


J. Environ. Nanotechnol., Volume 9, No 1 (2020) pp. 42-49

https://doi.org/10.13074/jent.2020.03.201399

PDF


Abstract

Crystallography is a fascinating division of the entire study of the optical technology. The single crystal of Phenyl trimethyl ammonium trichloro cadmiate (II) crystals [PTMAC (II)] was grown by slow evaporation technique at room temperature. The grown crystals were characterized using CHN analysis, FT-IR, 1H NMR spectra to confirm with functional groups and structures in spectroscopy methods. TG/TDA analysis were used to find out the thermal stability of grown crystals and fluorescence studies were also carried out, followed by single crystal X-ray diffraction studies by using SHELXL and refined by full matric latest square methods. The molecule belongs to monoclinic crystal system with C2i/n space group. Focus has been laid on the phase transition of crystals which makes the study interesting; moreover, inorganic crystals are being used for many applications in the field of computer technology.

Full Text

Reference


Asahi, T. and Hasebe, K., Measurement of monoclinic angle in the ferroelastic phase of [N(CH3)4]2XBr4(X=Zn, Co, Mn, Cd), J. Phys. Soc. Jpn, 63(7), 2827-2828(1994).

https://dx.doi.org/10.1143/JPSJ.63.2827

Blinc, R. and Lavanyak, A. P., Incommensurate Phases in Dielectrics : Materials 2, Elsevier Science publisher, 49(1986).

Dvorak, V. and Kind, R., On the low-temperature phase in Rb2Zncl4, Physical Status Solid B., 107, K109 (1981).

https://dx.doi.org/10.1002/pssb.2221070253

Fousek, J., Birefringence studies of A2BX4 compounds with incommensurate phases, Phase Transitions, 36(1-4), 165-190(1991).

https://dx.doi.org/10.1080/01411599108203438

Gesi, K., Effect of hydrostatic pressure on te phase transitions in tetraethylammonium tetrahalogenometallic compounds, Ferroelectrics, 159(1), 49-54(1986).

https://dx.doi.org/10.1080/00150199408007547

Hasebe, K., Mashiyama, H., Tanisaki, S. and Gesi, K., X – Ray study of the phase transitions in {N{CH3)4}2ZnBr4 and {N{CH3)4}2CoBr4, J. Phys. Soc. Jpn., 53(5), 1866-1868 (1984).

https://dx.doi.org/10.1143/JPSJ.53.1866

Heine, V. and McConnel, J. D., The origin of incommensurate structures in insulators, J. Physica C, 17(7), 1199 (1984).

https://dx.doi.org/10.1088/0022-3719/17/7/014

Kahirizi, M. and Steinitz, M. O., Atructural phase transitions in ((C2H5)4N)CdX4 and ((CH3)4N)2CdX4 compounds with X = Cl, Br, Solid State Communications, 70(6), 599-603(1989).

https://dx.doi.org/10.1016/0038-1098(89)90357-8

Kapustianik, V., Sveleba, S., Dacko, S., Vajdanych, V. and Mokryi, V., Dielectric properties of trimethylammonium tetrachlorcobaltate crystals, Phase transitions, 54, 131-136(1995).

https://dx.doi.org/10.1080/01411599508213224

Kasano, H., Takashige, M. and Mashiyama, H., J., Structure study of paraelectric-ferroelectric transition in Monoclinic K2ZnBr4, Phys. Soc. Jpn., 61(5),  1580 - 1584(1992).

https://dx.doi.org/10.1143/JPSJ.61.1580

Mashiyama, H., Hasebe, K. and Tanisaki, S., X – ray diffraction study on the incommensurate – commensurate phase transitions in {N(CH3)4}2CoCl4, J. Phy. Soc. Jpn, 49(4), Suppl. B, 92(1980).

https://dx.doi.org/10.1143/JPSJ.49.1633

Mohanraj, V., Pavithra, R., Thenmozhi, M. and Umarani, R., Synthesis, spectral, structural and thermal characterization of inorganic crystal : Phenyl trimethulammonium tetrachlorocobaltate, Asian J. Chem., 31(8), 1779-1784(2019b).

https://dx.doi.org/10.14233/ajchem.2019.21929

Peer Mohamed, M., Sudha, C., Jayaprakash, P., Vinitha, G., Nageswari, M., Sangeetha, P., Rathika ThayaKumari, C. and Lydia Caroline, M., Growth and characterization of L-histidinium fumarate fumaric acid monohydrate single crystal: A promising second and third order non linear optical material, Chinese J Phys, 60, 581-597(2019).

https://dx.doi.org/10.1016/j.cjph.2019.05.032

Sannikov, D. G. and Lavanyak, A. P., ‘Incommensurate Phases in Dielectrics’ 2, Elsevier Science publisher, 43(1986).

Sato, S., Ikeda, R. and Nakamura, D., Motions of tetramethylammonium cations and phase transitions in solid [(CH3)4N]2CdX4 (X = Cl, Br, I) as studied by 1H NMR, powder X-ray diffraction and differential thermal analysis measurements, Bull. Chem. Soc. Japan, 59(6), 1981 (1986).

https://dx.doi.org/10.1246/bcsj.59.1981

Sawada, S., Shiroshi, Y., Yamamoto, A., Takashige, M. and Mantuso, M., Ferroelectricity in {N(CH3)4}2 CoCl4, Physics Letters A., 67(1), 56-58(1978).

https://dx.doi.org/10.1016/0375-9601(78)90566-2

Shimomura, S., Fujii, Y. and Hamaya, N., Hydrostatic pressure effect on the ferroelastic monoclinic phase of [N(CH3)4]2MCl4 (M = Fe, Zn), Journal of the Physical Society of Japan, 64(12), 4759(1995).

https://dx.doi.org/10.1143/JPSJ.64.4759

Strukov, B. A., Global hysteresis in ferroelectrics with incommensurate phases, Phase Transitions, 15(2-3), 143-179(1989).

https://dx.doi.org/10.1080/01411598908206844

Subashini, R. and Arjun, S., Synthesis and physicochemical properties of bis(L-asparaginato) znic (II): A promising new semiorganic crystal  with high laser damage threshold for shorter wavelength generation, Optics and Laser Technology, 101, 248-256(2018).

https://dx.doi.org/10.1016/j.optlastec.2017.11.009

Contact Us

  • No. 53, II Street,
    Rock Mount City, Erode,
    TN, India - 638112
  • editorjent@gmail.com
  • +91 94422 64501

Powered by

Powered by OJS