Welcome to JENT its Thursday 18th of January 2018

Journal of Environmental Nanotechnology

(A Quarterly Peer-reviewed and Refereed International Journal)
ISSN(Print):2279-07 48; ISSN(Online):2319-5541
CODEN:JENOE2

Sol Gel Assisted Microwave Synthesised Hydroxyapatite Nanostructure using Biowaste Musselshell as A Calcium Source

Abstract

The common waste material from fish industry is Mussel shells which is normally disposed in land areas. The main composition of mussel shells is Mussels and aragonite. Hence it is considered as a by-product for producing nanomaterials. Nano Hydroxyapatite (n-HAp, Ca10(PO4)6(OH)2) has been prepared by microwave irradiation method using Mussel shell and Orthophosphoric acid as precursors at normal room temperature. Powder XRD results suggest that HAp are found to be hexagonal, P63/m symmetry, well matched with JCPDS card no: 09-0432. Restriction of particle growth was due to the substitution of capping agent EDTA while precipitation. FTIR predicts the presence of C-O and P-O stretching. The characterized sample is uniformly distributed, crystalline and elongated in nature. The morphology was identified to be spherical shaped by SEM micrographs with diameter of around 40 – 32 nm. EDAX reveals that it has standard Ca/P ratio 1.6. TEM reveals rod shaped Morphology.

Article Type: Research Article

Corresponding Author: V. Kalaiselvi 1  

Email: nk.arthikalai@gmail.com

This article has not yet been cited.

V. Kalaiselvi 1*,  R. Mathammal 2,  V. Vetrivel 3.  

1. Department of Physics, Navarasam Arts & Science College for Women, Erode, TN, India.

2. Department of Physics, Sri Sarada College for Women, Salem, TN, India.

3. 3Department of Physics, Sri Vasavi College of Arts & Science, Erode, TN, India.

J. Environ. Nanotechnol., Volume 6, No. 4 pp. 07-11
ISSN: 2279-0748 eISSN: 2319-5541
ENT174294.pdf
Download Citation

Reference

Amin Shavandi, Alaa El Din A. Bekhit , Azam Ali, Zhifa Sun, Synthesis of nano hydroxyapatite (nHA) from waste mussel shells using a rapid microwave method, Mater. Chem. Phys., 46(38), 607-616(2015).

doi:10.1016/j.matchemphys.2014.11.016.

Amogh Tathe, Mangeshghodke, Anna pratimanikalje, A Brief Review: Biomaterials and their application, Int. J. Pharm. Pharm. Sci., 2(4), 19-23(2010).

Gobi, D., Indira, J., Nithiya, S., Kavitha, L., Kmchi Mudali, U. and Kanimozhi, K., Influence of surfactant concentration on nano hydroxyapatite growth, Bull. Mater. Sci., 36(5), 799–805(2013).

doi:10.1007/s12034-013-0540-6.

Govindan Suresh Kumar, Easwaradas Kreedapathy Girija, Manickam Venkatesh, Gopalu Karunakaran, Evgeny Kolesnikov, Denis Kuznetsov, One step method to synthesize flower-like hydroxyapatite architecture using mussel shell bio-waste as a calcium source, Cera. Int., 43, 3457–3461(2017). 

doi:10.1016/j.ceramint.2016.11.163.

HadedAlobeedallah, Jeffrey L.Ellis, Preparation of nanostructured Hydroxyapatite in organic solvents for clinical application, Trends Biomaters., Artif. Organs., 25(1), 12-19(2011). 

Haresh M. Pandya and Anitha, P., Comprehensive Review of Preparation Methodologies of Nano Hydroxyapatite, J. Environ. Nanotechnol., 3(1), 101-121(2013).

doi:10.13074/jent.2013.12.132058.

Haresh M.Pandya., Modelling Scenario in Nanotechnology Today, J. Environ. Nanotechnol., 1(1), 01-04 (2012). 

doi. 10.13074/jent.2012.10.121020 .

Kalaiselvi, V. and Mathammal, R., Effect of Titanium Dioxide Doping on Nano Hydroxyapatite Synthesised From Egg Shells Via Wet Chemical Method, Int. J. Mag. Eng. Technol. Manag. Res., 3(8), 133-138(2016).

Kanchana, P. and Sekar, C., EDTA assisted synthesis of hydroxyapatite nanoparticles for electrochemical sensing of uric acid, Mater. Sci. Eng. C., 42, 601–607(2014).

doi:10.1016/j.msec.2014.05.072.

Kapoor Seema, Batra Uma and Kohli Suchita, Transformation in sol-gel synthesized nanoscale Hydroxyapatite calcined under different temperatures and Time conditions, J. Mater. Eng. Perform., 21(8), 1737-1743(2011).

doi: 10.1007/s11665-011-0059-1

Koumoulidis, G. C. and Katsoulidis, A. P., Preparation of Hydroxyapatite via micro emulsion route, J. Colloid. Interf. Sci., 259(2), 254-260(2003).

doi:10.1016/S0021-9797(02)00233-3

Mark I Jones, Haneen Barakat, Darrell Alec Patterson, Production of hydroxyapatite from waste mussel shells, ICC3: Symposium 13: Ceramics for Medicine, Biotechnology and Biomimetics, IOP Publishing IOP Conf. Series: Mater. Sci. Eng., 18(13), 2002 (2011).

doi:10.1088/1757-899X/18/19/192002.

Sahil Jalota, Cuneyt Tass, A. and Sarit BBhaduri., Microwave assisted synthesis of calcium phosphate nanowhiskers, J. Mater. Res., 19(6), 1876-1881(2004).

doi:10.1557/JMR.2004.0230.

Sanosh, K. P., Min Cheolchu, Balakrishnan, A., Kim, T. N. and Seong Jai Cho., Preparation and characterization of nano hydroxyapatite powder using solgel technique, Bull. Mater. Sci., 32(5), 465-470 (2009).

doi:10.1007/s12034-009-0069.

Sopyan, I., Nawawi, N. A., Shah, Q., Singh R., Tan, C. Y. and Hamdi, M., Sintering and properties of Dense Manganese doped calcium phosphate Bioceramics prepared using sol-gel derived nanopowder, Mater. Manuf. Processes., 26(7), 908-914(2011).

doi:10.1080/10426914.2011.557285

 

>>