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Journal of Environmental Nanotechnology

(A Quarterly Peer-reviewed and Refereed International Journal)
ISSN(Print):2279-07 48; ISSN(Online):2319-5541
CODEN:JENOE2

Electrochemical Synthesis of Aluminium Hydride for Hydrogen Storage

Abstract

Electrochemical Synthesis of Aluminium hydride material was gaining interest due to usage in storing hydrogen for automobiles. Biofuel reduces pollution and various cardiac diseases all over the world. The most preferred method was Electrochemical Synthesis. The chemical method degrades the particles in three days. So the Electrochemical Synthesis was the best way to prepare Aluminium Hydride. The chemicals used were Sodium Aluminium Hydride as electrolyte, Tetrahydrofuran (THF) as a solvent and it was toxic. It was performed in Argon atmosphere. Aluminium Hydride (Alane) formed in the form of pore which gets evaporated within few seconds

Article Type: Research Article

Corresponding Author: B. Nirmala 2  

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This article has not yet been cited.

G. Saraswathi 1,  B. Nirmala 2*,  R. Rajalakshmi 3.  

1, 2. Department of Physics, Sri GVG Visalakshi College for Women, Udumalpet, TN, India.

3. International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Chennai,TN, India.

J. Environ. Nanotechnol., Volume 6, No. 1 pp. 34-38
ISSN: 2279-0748 eISSN: 2319-5541
ENT171224.pdf
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Reference

David Lacina, Liu Yang, Irinder Chopra, James Muckerman, Yves Chabal and Jason Graetz, Investigation of LiAlH4- THF formation by direct hydrogenation of catalyzed Al and LiH,  Phys. Chem. Chem. Phys., 14(18), 6569-6576(2012).

doi:10.1039/c2cp40493a

Graetz, J. and Reilly, J. J., Decomposition kinetics of the AlH3 polymorphs, J. Phys. Chem. B., 109(47), 22181-22185(2005).

doi: 10.1021/jp0546960

Jason Graetz, James Wegrzyn and Reilly J. James, Regeneration of Lithium aluminium hydride, J. Am. Chem. Soc., 130(52), 17790-17794(2008).

doi:10.1021/ja805353w

Liu Xiangfeng,  McGrady G. Sean, Langmi  H. W. and Jensen Craig, M., Facile cycling of Ti-doped LiAlH4 for high performance hydrogen storage, J. Am. Chem. Soc., 131(14), 5032-5033(2009).

doi:10.1021/ja809917g

Ragaiy Zidan, Joe Teprovich, Douglas A. Knight and Scott Greenway,  Electrochemical Reversible Formation of Alane,(2012).

Ragaiy Zidan, Brenda L. Garcia-Diaz, Christopher S. Fewox, Ashley C. Stowe, Joshua R. Gray and Andrew G. Harter, Aluminium hydride: A reversible material for hydrogen storage, Chem. Commun., 114(25), 3717-3719, (2009).

doi:10.1039/b901878f

Sandrock, G., Reilly, J.,  Graetz, J., Zhou, W. M., Johnson, J. and  Wegrzyn, J., Alkali metal hydride doping of α–AlH3 for enhanced H2 desorption kinetics,  J. Alloys Compd., 421(1-2), 185-189(2006).

doi:10.1016/j.jallcom.2005.09.081

Senoh, H.,  Kiyobayashi, T., Kuriyama, N., Tatsumi, K. and Yasuda, K., Electrochemical reaction of lithium alanate dissolved in diethyl ether and tetrahydrofuran,  J. Power Sources, 164(1), 94-99(2007).

doi:10.1016/j.jpowsour.2006.10.034

Senoh, H., Kiyobayashi, T. and Kuriyama, N., Hydrogen electrode reaction of lithium and sodium aluminium hydrides, Int. J. Hydrogen Energy, 33(12), 3178-3181(2008).

doi:10.1016/j.ijhydene.2008.01.019

Zhang Huajun, Exploration of New Technologies for hydrogen storage, National University of Singapore,(2011).

 

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