Open Access

Comparison of Various Characteristics Activated Carbon Prepared from Turmeric Industrial Waste through Different Activation Processes

K. T. Karthikeyan , Department of Chemistry, M.A.M. College of Engineering, Trichy, TN, India. K. Mabel Hebsuba , Department of Chemistry, Sasuri College of Engineering, Tiruppur, TN, India. K. Jothivenkatachalam keteeke@gmail.com
Department of Chemistry, BIT campus, Anna University, Trichy, TN, India.


J. Environ. Nanotechnol., Volume 5, No 1 (2016) pp. 17-25

https://doi.org/10.13074/jent.2016.03.161182

PDF


Abstract

Different characteristics activated carbons were prepared from turmeric industrial waste by using various carbonization and activation methodology and the surface characteristics were determined using standard analytical methods. The difference in the pore volume of activated carbons was obtained by various activating agents used during the activation processes. The surface area and pore size volumes for the different activated carbon samples were estimated by nitrogen adsorption measurements at 77 K. The morphology of the newly prepared carbon sample was studied by scanning electron microscopy, the surface functional groups were investigated by Fourier transformation infrared spectroscopy techniques and the presence of graphitic structure were studied by X-Ray diffraction analysis. Physico-chemical characteristics such as bulk density, moisture content, ash content, matter soluble in water, matter soluble in acid, pH, iodine number, conductivity, porosity, pHzpc, yield percentage and surface area were investigated to chose the suitability of the carbon as adsorbent for the dye removal processes. In this study, the results clearly proves that the activated carbon prepared from turmeric industrial waste by using H2SO4 carbonization process followed by activation at 800 °C under nitrogen atmosphere chosen as the suitable adsorbent possessing highest surface area with better pore volume and iodine number for the removal of textile dyes from aqueous solution.

Full Text

Reference


Adinata, D., Wan Daud, W. M. and Aroua, M. K., Preparation and characterization of activated carbon from palm shell by chemical activation with K2CO3, Bioresour. Technol., 98(1), 145-149(2007).

http://doi.org/10.1016/j.biortech.2005.11.006

Alaerts, G. J., Jitjaturunt, V. and Kelderman, P., Use of coconut shell-based activated carbon for chromium(VI) removal, Wat. Sci. Techn., 21(12), 1701-1704(1989).

Allen, S. J., McKay, G. and Khader, K. Y., Intraparticle diffusion of a basic dye during adsorption onto sphagnum peat, Environ. Pollut., 56(1), 39-50(1989).

Babel, S. and Kurniawan, T. A., Low-cost adsorbents for heavy metals uptake from contaminated water: a review, J. Hazard Mater., 97(1-3), 219-243(2003).

http://doi.org/10.1016/S0304-3894(02)00263-7

Bansal, R. C., Diksha Agarwal, Meenakshi Goyal, Kaistha, B. C., Influence of carbon-oxygen surface groups on the adsorption of phenol by activated carbons, Ind. J. Chem. Technol., 9, 290-296(2002).

Gregg, S. J and Sing, K. S. W., Adsorption, Surface Area and Porosity (2nd Edition), Academic Press, London, (1982).

Hu, Z and Srinivasan, M. P., In: 5th International Activated Carbon Technology Board of Singapore (NSTB) under a grant for Conference, the Pittsburgh Plaza, Pittsburgh, USA(1997).

Karthikeyan, S. and Sivakumar, P., The effect of activating agents on the activated carbon prepared from Ferronia limonia (L.) swingle wood apple shell, J. Environ.Nanotechnol., 1(1), 1-5(2012).

http://doi.org/10.13074/jent.2012.20.121009

Karthikeyan, S., Bhuvaneswari, G., Malathi, S., Maheswari, P. and Sivakumar, B., Studies on removal of textile effluents using Ipomoea carnea stem waste activated carbon, J. Ind. Council Chem. 24(2), 63-67(2007).

Kendall, D., Applied infrared spectroscopy, Reinhold Publishing Corp. Chapman & Hall Ltd, London, 560(1996).

Khattri. S. D, M. K. Singh, Adsorption of basic dyes from aqueous solution by natural adsorbent, J. Chem. Technol., 6(2), 112-116(1999).

Manju, G.N., Raji, C. and Anirudhan, T.S., Evaluation of coconut husk carbon for the removal of arsenic from water, Water Res. 32(10), 3062–3070(1998).

http://doi.org/10.1016/S0043-1354(98)00068-2

Pereira, M. F. R., Soares, S. F., Orfao, J. J. M. and Figureueiredo, J. L., Adsorption of dyes on activated carbons: influence of surface chemical groups, Carbon, 41(4), 811-821(2003).

http://doi.org/10.1016/S0008-6223(02)00406-2

Martin. J. B, (USEPA), Federal Register, 77, 58(2012).

Namasivayam, C. and Periasamy, K., Bicarbonate treated peanut hull carbon for mercury(II) removal from aqueous solution, Water Res., 27(11), 1663-1668(1993).

http://doi.org/10.1016/0043-1354(93)90130-A

Raffiea Baseri, J., Palanisamy, P. N and Sivakumar, P., Preparation and characterization of activated carbon from Thevetia peruviana for the removal of dyes from textile waste water, Adv. App. Sci. Res., 3 (1), 377-383(2012).

Sivakumar, B., Kannan, C and Karthikeyan, S., Preparation and characterization of activated Carbon prepared from Balsamodendron caudatum wood waste through various activation processes, Rasayan J. Chem., 5(3), 321-327(2012).

Youseff, A.. M., Mostafa, M. R. and Dorgham, E. M., Surface properties of decolorizing power of carbons from rice husk, Afinidad., 47(425), 41-44(1990).

Zawndski, J., IR spectroscopy investigations of acidic character of carbonaceous films oxidized with HNO3 solution, Carbon, 19(1), 19-25(1981).

http://doi.org/10.1016/0008-6223(81)90100-7

Contact Us

  • No. 53, II Street,
    Rock Mount City, Erode,
    TN, India - 638112
  • editorjent@gmail.com
  • +91 94422 64501

Powered by

Powered by OJS