Open Access

Synthesis of BiVo4 Nanoparticle by Additive Assisted Microwave Hydrothermal Method and its Photocatalytic Performances

Moscow Subramanian, Department of Chemistry, Anna University, BIT Campus, Tiruchirappalli, Tamilnadu, India. Jothivenkatachalam jothivenkat@yahoo.com
Department of Chemistry, Anna University, BIT Campus, Tiruchirappalli, Tamilnadu, India.


J. Environ. Nanotechnol., Volume 4, No 4 (2015) pp. 31-35

https://doi.org/10.13074/jent.2015.12.154169

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Abstract

Monoclinic bismuth vanadate nanoparticle (BiVO4) have been synthesized in the presence of ethylenediaminetetraacetic acid (EDTA) using the microwave hydrothermal method. The as-synthesized samples were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and UV-Vis diffuse reflectance spectroscopy (UV-vis DRS). The photocatalytic activity of the as-prepared samples was evaluated towards degradation of Rhodamine B (RhB) by visible-light. Our results indicate that the photocatalytic activity of BiVO4 nanoparticles is enhanced by addition of EDTA.

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Reference


Fujishima, A. and Honda, K., Electrochemical photolysis of water at a semiconductor electrode, Nat., 238, 37-38(1972).

doi:10.1038/238037a0

Guo, Y., Yang, X., Ma, F., Li, K., Xu, L., Yuan, X. and Guo, Y., Additive-free controllable fabrication of bismuth vanadates and their photocatalytic activity toward dye degradation, Appl. Surf. Sci., 256, 2215-2222(2010).

doi:10.1016/j.apsusc.2009.09.076

Kudo, A., Kato, H. and Tsuji, I., Strategies for the development of visible-light-driven photocatalysts for water splitting, Chem. Lett., 33, 1534-1539(2004).

doi:10.1246/cl.2004.1534 

Malato, S., Blanco, J., Alarcón, D. C., Maldonado, M. I.,  Fernández Ibáñez, P. and Gernjak, W., Photocatalytic decontamination and disinfection of water with solar collectors, Catal. Today, 122, 37-149(2007).

doi:10.1016/j.cattod.2007.01.034 

Martínez-de la Cruz, A. and García Pérez, U. M., Photocatalytic properties of  BiVO4 prepared by the co-precipitation method: Degradation of rhodamine B and possible reaction mechanisms under visible irradiation, Mater. Res. Bull., 45, 135-141(2010).

doi:10.1016/j.materresbull.2009.09.029

Martínez-de la Cruz, A. and Obregón Alfaro, S., Synthesis and characterization of γ-Bi2MoO6 prepared by co-precipitation: Photoassisted degradation of organic dyes under vis-irradiation, Mol. Catal. A: Chem., 320, 85-91(2010).

doi:10.1016/j.molcata.2010.01.008

Meng, X., Zhang, L., Dai, H., Zhao, Z., Zhang, R. and Liu, Y., Surfactant-assisted hydrothermal fabrication and visible-light-driven photocatalytic degradation of methylene blue over multiple morphological BiVO4 single-crystallites, Mater. Chem. Phys., 125, 59-65(2011).

doi:10.1016/j.matchemphys.2010.08.071

Peral, J. and Ollis, D. F., TiO2 photocatalyst deactivation by gas-phase oxidation of heteroatom organics, J. Mol. Catal. A: Chem., 115(2), 347-354(1997).

doi:10.1016/S1381-1169(96)00330-5

Shang, M., Wang, W., Zhou, L., Sun, S. and Yin, W., Nanosized BiVO4 with high visible-light-induced photocatalytic activity: Ultrasonic-assisted synthesis and protective effect of surfactant, J. Hazard. Mater., 172(1), 338-344(2009).

doi:10.1016/j.jhazmat.2009.07.017

Shang, M., Wang, W., Ren, J., Sun, S. and Zhang, L., A novel BiVO4 hierarchical nanostructure: Controllable synthesis, growth mechanism and application in photocatalysis, Cryst. Eng. Comm., 12, 1754-1758(2010).

doi:10.1039/b923115c

Sun, S., Wang, W., Zhou, L. and Xu, H., Efficient methylene removal over hydrothermally synthesized star like BiVO4, Ind. Eng. Chem. Res., 48, 1735-1739(2009).

doi:10.1021/ie801516u

Sun, Y., Xie, Y., Wu, C. and Long, R., First experimental identification of BiVO4-0.4 H2O and its evolution mechanism to final monoclinic BiVO4, Cryst. Growth. Des., 10, 602-607(2010).

doi:10.1021/cg900988j

Yang, T., Xia, D., Chen, G. and Chen, Y., Influence of the surfactant and temperature on the morphology and physico-chemical properties of hydrothermally synthesized composite oxide BiVO4, Mater. Chem. Phys., 114, 69-72(2009).

doi:10.1016/j.matchemphys.2008.08.005

Yin, W., Wang, W., Zhou, L., Sun, S. and Zhang, L., CTAB-assisted synthesis of monoclinic BiVO4 photocatalyst and its highly efficient degradation of organic dye under visible-light irradiation, J. Hazard. Mater., 173, 194-199(2009).

doi:10.1016/j.jhazmat.2009.08.068

Yu, J. and Kudo, A., Effects of Structural Variation on the photocatalytic performance of hydrothermally synthesized BiVO4, Adv. Funct. Mater., 16, 2163-2169(2006).

doi:10.1002/adfm.200500799

Yuy, J. and Kudo, A., Hydrothermal synthesis nano-fibrous bismuth vanadate, Chem. Lett., 34, 850-851(2005).

doi:10.1246/cl.2005.850

Zhang, L., Chen, D. and Jiao, X., Monoclinic structured BiVO4 nanosheets: Hydrothermal preparation, formation mechanism and coloristic and photocatalytic properties, J. Phys. Chem. B., 110, 2668(2006).

doi:10.1021/jp056367d

Zhang, X., Ai, Z., Jia, F., Zhang, L., Fan, X. and Zou, Z., Selective synthesis and visible-light photocatalytic activities of BiVO4 with different crystalline phases, Mater. Chem. Phys., 103(1), 162-167(2007).

doi:10.1016/j.matchemphys.2007.02.008

Zhang, Z., Wang, W., Shang, M. and Yin, W., Photocatalytic degradation of rhodamine B and phenol by solution combustion synthesized BiVO4 photocatalyst, Catal. Commun., 11, 982-986(2010).

doi:10.1016/j.catcom.2010.04.013

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