Open Access

Photocatalytic Decolorization of Textile Effluent by using Synthesized Nano particles

Narayanappa Madhusudhana, Department of P.G studies and Research in Environmental Science, Kuvempu University, JnanaSahyadri, Shankaraghatta, Shivamogga, Karnataka, India. Kambalagere Yogendra, madhubdvt@gmail.com
Department of P.G studies and Research in Environmental Science, Kuvempu University, JnanaSahyadri, Shankaraghatta, Shivamogga, Karnataka, India.
Kittappa M. Mahadevan Department of Chemistry, Kadur P.G Center, Kuvempu University, Kadur, Karnataka, India.


J. Environ. Nanotechnol., Volume 3, No 4 (2014) pp. 41-53

https://doi.org/10.13074/jent.2014.12.143109

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Abstract

The textile industry consumes considerable amounts of water during the dyeing and finishing operations. Dyes extensively used are found to be toxic and considered to be resistant to biodegradation. In this work, a detailed investigation was done on photocatalytic degradation for selected textile effluent. The two different nano particles, CaAl2O4-I was synthesized by using fuel urea and CaAl2O4-II by acetamide by solution combustion method. These nano particles were characterized by using X-ray diffraction (XRD), Scanning Electron Micrograph (SEM) and UV absorbance spectroscopy. The average size was found to be 39 nm for CaAl2O4-I and 42 nm for CaAl2O4-II. The band gap of the nano particle CaAl2O4-I was found to be 2.8 eV and CaAl2O4-II was 2.7 eV. These nano particles were tested for the photocatalytic degradation by varying parameters such as catalyst concentration, pH and dye concentration. Also, the efficiency of the synthesized nano particles were compared with the procured TiO2 of size < 25 nm.

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Reference


ehnajady, A., Modirshahla, N. and Hamzavi, R.,&nbsp;Kinetic study on photocatalytic degradation of&nbsp;C. I. Acid Yellow 23 by ZnO photocatalyst, J.&nbsp;Hazard. Mater., B, 133 (1-3), 226-232(2006).

Byrappa, K., Subramani, A. K., Ananda, S.,&nbsp;LokanathaRai, K. M., Dinesh, R. and Yoshimura,&nbsp;M., Photocatalytic degradation of Rhodamine B&nbsp;dye using hydrothermally synthesized ZnO, Bull.&nbsp;Mater. Sci., 29 (5), 433-438(2006).&nbsp;

doi:10.1007/BF02914073

Da-Silva, C. G., and Faria, J. L., Photochemical and&nbsp;photocatalytic degradation of an azo dye in&nbsp;aqueous solution by UV irradiation, J.&nbsp;Photochem. Photobiol., A, 155 (1-3), 133-143(2003).

Deshpande, K., Mukasyan, A. M. and Varma, A.,&nbsp;Direct synthesis of iron oxide nano powders by&nbsp;the combustion approach: reaction mechanism&nbsp;and properties, Chem. Mater., 16 (24), 4896-&nbsp;4904(2004).

doi:10.1021/cm040061m

Di-Paola, A., Augugliaro, V., Palmisano, L., Pantaleo,&nbsp;G. and Savinov, E., Heterogeneous photocatalytic&nbsp;degradation of nitrophenols, J. Photochem.&nbsp;Photobiol., A, 155 (1-3), 207-214(2003).

Girase, K. D., Patil, H. M., Sawant, D. K. and&nbsp;Bhavsar, D. S., Effect of Cu2+ Doping on the Growth and Band Gap Energy of Nano Crystals&nbsp;of Lead Iodate, Arch. Appl. Sci. Res., 3 (3), 128&ndash;&nbsp;134(2011).

Giwa, A., Nkeonye, P. O., Bello, K. A., Kolawole, E.&nbsp;G. and Oliveira Campos, A. M. F., Solar Photocatalytic Degradation of Reactive Yellow&nbsp;81 and Reactive Violet 1 in Aqueous Solution&nbsp;Containing Semiconductor Oxides, Int. J. Appl.&nbsp;Sci. Technol., 2 (4), 90-105(2012).

Gopalappa, H., Yogendra, K., Mahadevan, K. M. and&nbsp;Madhusudhana, N., A comparative study on the&nbsp;solar photocatalytic degradation of Brilliant red&nbsp;azo dye by CaO and CaMgO2 nano particles, Int.&nbsp;J. Sci. Res., 1 (2), 91-95(2012).

Gopalappa, H., Yogendra, K., Mahadevan, K. M. and&nbsp;Madhusudhana, N., Solar Photocatalytic&nbsp;degradation of Orange G (mono azo dye) and&nbsp;C. I. Direct Yellow 50 (di azo dye) by synthesized&nbsp;CaZnO2 nano particle in aqueous solution, Int. J.&nbsp;Univ. Pharm. Life Sci., 2 (4), 66-77(2012).

Gouvea, C. A. K., Wypych, F., Moraes, S. G., Duran,&nbsp;N., Nagata, N. and Peralta-Zamora, P.,&nbsp;Semiconductor-assisted photocatalytic&nbsp;degradation of reactive dyes in aqueous solution,&nbsp;Chemosphere, 40 (4), 433-440(2000).

doi:10.1016/S0045-6535(99)00313-6


Khodja, A. A., Sehili, T., Pilichowski, J. F. and Boule,&nbsp;P., Photocatalytic degradation of 2-phenylphenol&nbsp;on TiO2 and ZnO in aqueous suspensions, J.&nbsp;Photochem. Photobiol., A, 141 (2-3), 231-&nbsp;239(2001).

Lizama, C., Freer, J., Baeza, J. and Mansilla, H. D.,&nbsp;Optimized photodegradation of reactive Blue 19&nbsp;on TiO2 and ZnO suspensions, Catal. Today, 76&nbsp;(2-4), 235-246(2002).

doi:10.1016/S0920-5861(02)00222-5

Madhusudhana, N., Yogendra, K. and Mahadevan, K.&nbsp;M., A comparative study on Photocatalytic&nbsp;degradation of Violet GL2B azo dye using CaO&nbsp;and TiO2 nano particles, Int. J. Eng. Res. Appl., 2&nbsp;(5), 1300-1307(2012).

Madhusudhana, N., Yogendra, K. and Mahadevan, K.&nbsp;M., Photocatalytic degradation of Violet GL2B&nbsp;azo dye by using Calcium aluminate nano particle&nbsp;in presence of solarlight, Res. J. Chem. Sci., 2 (5),&nbsp;72-77(2012).

Madhusudhana, N., Yogendra, K. and Mahadevan, K.&nbsp;M., Photocatalytic Decolourization of Textile&nbsp;Effluent by Using Metal Oxide Nano particles, J.&nbsp;Sci. Arts, 3 (24), 303-318(2013).

Madhusudhana, N., Yogendra, K., Mahadevan, K. M.,&nbsp;and SuneelNaik, Photocatalytic degradation of&nbsp;Coralene Dark Red 2B azo dye using Calcium&nbsp;zincate as an nano particle in presence of natural&nbsp;sunlight: An aid to environmental remediation,&nbsp;Int. J. Chem. Eng. Appl., 2 (4), 301-305(2011).

Malato, S., Blanco, J., Vidal, A. and Richter, C.,&nbsp;Photocatalysis with solar energy at a pilot-plant&nbsp;scale: an overview, Appl. Catal., B, 37 (1), 1-15(2002).

doi:10.1016/S0926-3373(01)00315-0

Manjusha, K. and Pragati, T., Photocatalytic&nbsp;Degradation and Mineralization of Reactive&nbsp;Textile Azo Dye Using Semiconductor Metal&nbsp;Oxide Nano Particles, Int. J. Eng. Res. Gen. Sci.,&nbsp;2 (2), 245-254(2014).

Mimani, T. and Patil, K.C., Solution combustionsynthesis of nanoscale oxides and their&nbsp;composites, Mater. Phy. Mech., 4 (1), 134-137(2001).

Mirkhani, V., Tangestaninejad, S., Moghadam, M.,Habibi, M. H. and Rostami Vartooni, A.,&nbsp;Photocatalytic Degradation of Azo DyesCatalyzed by Ag Doped TiO2 Photocatalyst, J.
Iranian Chem. Soc., 6 (3), 578-587(2009).

doi:10.1007/BF03246537

Mohammad, H. H., Ali, H. and Mahdavi, S., The&nbsp;effect of operational parameters on the&nbsp;photocatalytic degradation of three textile azo&nbsp;dyes in aqueous TiO2 suspensions, J. Photochem.&nbsp;Photobiol., A, 172 (1), 89-96(2005).

Nesaraj, A. S., Arul Raj, I. and Pattabiraman, R.,&nbsp;Synthesis and characterization of LaCoO3 based&nbsp;cathode and its chemical compatibility with CeO2&nbsp;based electrolytes for Intermediate Temperature&nbsp;Solid Oxide Fuel Cell (ITSOFC), Indian J. Chem.&nbsp;Technol., 14 (1), 154-160(2007).

Noorjahan, M., Pratap Reddy, M., DurgaKumari, V.,&nbsp;Lavedrine, B., Boule, P. and Subrahmanyam, M.,&nbsp;Photocatalytic degradation of H-acid over a novel&nbsp;TiO2 thin film fixed bed reactor and in aqueous&nbsp;suspensions, J. Photochem. Photobiol., A, 156 (1-&nbsp;3), 179-187 (2003).

Sawant, D. K., Patil, H. M., Bhavsar, D. S., Patil, J. H.&nbsp;and Girase, K. D., Structural and Optical&nbsp;Properties of Calcium Cadmium Tartrate, Arch.&nbsp;Phys. Res., 2, 67-73 (2011).

Subramani, A. K., Byrappa, K., Ananda, S.,&nbsp;LokanathaRai, K. M., Ranganathaiah, C. and&nbsp;Yoshimura, M., Photocatalytic degradation of&nbsp;indigo carmine dye using TiO2 impregnated
activated carbon, Bull. Mater. Sci., 30 (1): 37-41&nbsp;(2007).

doi:10.1007/s12034-007-0007-8

Swati., Munesh. and Meena, R. C., Photocatalytic&nbsp;degradation of textile dye through an alternative&nbsp;photocatalyst methylene blue immobilized resin&nbsp;dowex 11 in presence of solar light, Arch. Appl.&nbsp;Sci. Res., 4 (1), 472-479 (2012).

Turchi, C. S. and Ollis, D. F., Photocatalytic&nbsp;Degradation of Organic Water Contaminants:&nbsp;Mechanisms Involving Hydroxyl Radical Attack,&nbsp;J. Catal., 122 (1), 178-192 (1990).

doi:10.1016/0021-9517(90)90269-P

Yeber, M. C., Rodriguez, J., Freer, J., Duran, N. and&nbsp;Mansilla, H. D., Photocatalytic degradation of&nbsp;cellulose bleaching effluent by supported TiO2&nbsp;and ZnO, Chemosphere, 41 (8), 1193-1197(2000).

doi:10.1016/S0045-6535(99)00551-2

Yogendra, K., Suneel Naik, Mahadevan, K. M., and&nbsp;Madhusudhana, N., A comparative study of&nbsp;photocatalytic activities of two different&nbsp;synthesized ZnO composites against Coralene&nbsp;Red F3BS dye in presence of natural solar light,&nbsp;Int. J. Environ. Sci. Res., 1 (1), 11-15 (2011).

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