Open Access

Kinetics of Adsorption of Congo Red Dye onto Commercial Activated Carbon from Aqueous Solution

A. Rajappa, Department of Chemistry, Sri Manakula Vinayagar Engineering College, Puducherry,india K. Ramesh, Department of Chemistry, Arasu Engineering college, Kumbakonam,india V. Nandhakumar, vnchem13@gmail.com
Department of Chemistry, A.V.V.M SriPushpam college, Poondi,india
Hema Ramesh Department of Chemistry, Sri Manakula Vinayagar Engineering College, Puducherry,india


J. Environ. Nanotechnol., Volume 3, No 2 (2014) pp. 43-49

https://doi.org/10.13074/jent.2014.03.142067

PDF


Abstract

Adsorption of Congo Red dye (CR) onto Commercial Activated Carbon (CAC) from aqueoussolution was investigatedundervariousexperimentalconditions.Batchmode experimentswereconducted. The pHzpc of CAC was 6. Hence all experiments were carried out at solution pH 6. Experimental data were fitted with linearised forms of Lagergren and Ho kinetic equations for pseudo first order and pseudo second order models respectively. Rate constants and theoretical adsorption capacities were calculated. The SumofErrorSquares Percentage (SSE %) for first order and second order kinetics were 3.57 & 7.05 respectively and hence this adsorption followed first order kinetics. Adsorption capacities of CAC, estimated from equilibrium studiesfor different initialconcentrations ofadsorbate were found to be good.

Full Text

Reference


Alau, K. K., Gimba, C. E. and J. A. Kagbu., Removal of dyes fr om aqueous solution using Neem (AzadirachtaIndica) Husk as Activated Carbon, Archives of Appl.Sci. Res., 2(5), 456 - 461(2010).

Gongo, R., Jin,Y., Chen,J., Hu, Y. and Sun, J., Removal of basic dyes from aqueous solution by sorption on phosphoric acid modified rice straw, Dyes Pigments., 73, 332-337 (2007). 

http://dx.doi.org/10.1016/j.dyepig.2006.01.037

Gupta, V. K., Mittal, A., Krishnan, L. and Gajbe,V., Adsorption kinetics and column operations for the removal and recovery of malachite green from waste water using bottom ash, Sep. Purif. Technol., 40(1), 1179-1184 (2004). 

http://dx.doi.org/10.1016/j.seppur.2004.01.008

Gupta, V. K., Suhas, A. I., Saini, V. K., Removal of rhodamineB, fast green and methylene blue from wastewater using red mud, an aluminum industry waste, Ind. Eng. Chem. Res.,43, 1740-1747 (2004). 

http://dx.doi.org/10.1021/ie034218g

Hameed,B. H., Din, A.T. M.,Ahmad,A. L., Adsorption of methylene blue onto bamboo-based activated car bon: kinetics and equilibr ium studies.J.HazardMater.,141(3), 819-825 (2006).

Jia, Y. F. and Thomas, K. K., Adsorption of metal ion on nitrogen surface functional groups in activated carbon,Langmuir.,18(2), 470 (2002). 

http://dx.doi.org/10.1021/la011161z

Mansour, M. S., Ossman, M. E. and Farag, H. A., Removal of Cd (II) ion from waste water by adsorption onto polyaniline coated on sawdust, Desalination., 272(1-3), 301-305 (2011). 

http://dx.doi.org/10.1016/j.desal.2011.01.037

Namasivayam, C., Kavitha, D., Adsorptive removal of 2-chlorophenol by low-cost coir pith carbon, J. Hazard. Mater., 98(1-3), 257-274 (2003). 

http://dx.doi.org/10.1016/S0304-3894(03)00006-2

Namasivayam, C., Kavitha, D., Removal of Congo red from water by adsorption onto activated carbon prepared from coir pith and agricultural solid waste, Dyes Pigments., 54, 47-58 (2002).

http://dx.doi.org/10.1016/S0143-7208(02)00025-6

Ricarto, A., Carletto, F., Bosco and Ferrero, F., Adsorption of congo red dye on Hazelnut shells and degradation with Phanerochattechrysosprium, Bio Resources., 3 (4), 1146-1155 (2008).

Siew-Teng, O., Lee,W., Keng, P., Hung, Y. and Ha, S., Equilibriun studies and kinetics mechanism for the removal of basic and reactive dyes in both single and binary systems using EDTA modified rice husk, Intl. J. Physical sci., 5(5), 582 - 595 (2010)

Srivastava, K., Balasubramanian, N. and Ramakrishna, T. V., Studies on chromium removal by rice husk carbon,Indian J. Environ. Health.,30(4), 376 -387 (1988).

Sudipta, C., Lee, D. S., Lee, M. W. and Woo, S. H., Enhanced adsorption of congo red from aqueous solution by chitosan hydrogel beads impregnated with cetyltrimethyl ammonium bromide, Bioresour. Technol., 100, 2803-2809 (2009). 

http://dx.doi.org/10.1016/j.biortech.2008.12.035

Tahir, H., Sultan, M. and Jahanzeb, Q., Remediation of azo dyes by using household used black tea as an absorbent, Afr. J. Biotechnol., 8(15), 3584-3589 (2009).

Venkatraman, B.R.,Hema, K.,Nandhakumar, V. and Ari vol i, S. , Adsor p t i on Th er modyn am i c sof Mal achiteGreenDye onto Acid Activa t edLow CostCarbon, J.Chem.Pharm.Res., 3(2), 637-649 (2009).

Contact Us

  • No. 53, II Street,
    Rock Mount City, Erode,
    TN, India - 638112
  • editorjent@gmail.com
  • +91 94422 64501

Powered by

Powered by OJS